catena-Poly[[[triaqua[3-(4-carboxyphenoxy)phthalato-κO2]manganese(II)]-μ-4,4′-bipyridine-κ2N:N′] 4,4′-bipyridine monosolvate dihydrate]
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چکیده
منابع مشابه
catena-Poly[[[triaqua[3-(4-carboxyphenoxy)phthalato-κO 2]manganese(II)]-μ-4,4′-bipyridine-κ2 N:N′] 4,4′-bipyridine monosolvate dihydrate]
In the title compound, {[Mn(C(15)H(8)O(7))(C(10)H(8)N(2))(H(2)O)(3)]·C(10)H(8)N(2)·2H(2)O}(n), the bridging mode of the coordinating 4,4'-bipyridine ligands leads to the formation of polymeric zigzag chains parallel to [0-11]. The chains are separated by 4,4'-bipyridine and water solvent mol-ecules. Within a chain, the Mn(II) atom is six-coordinated by two N atoms of the bridging 4,4'-bipyridin...
متن کاملcatena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2 N:N′] bis(perchlorate) 4,4′-bipyridine disolvate dihydrate]
In the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](ClO(4))(2)·2C(10)H(8)N(2)·2H(2)O}(n), slightly distorted octa-hedrally coordinated Co(II) ions situated on inversion centers are linked into polycationic chains through 4,4'-bipyridine tethering ligands. These are connected into supra-molecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water mol-...
متن کاملcatena-Poly[[[bis(μ-4-hydroxybenzoato)bis[(4-hydroxybenzoato)manganese(II)]]-di-μ-4,4′-bipyridine] 4,4′-bipyridine disolvate tetrahydrate]
In the polymeric title complex, {[Mn(O(2)CC(6)H(4)-p-OH)(2)(C(10)H(8)N(2))]·C(10)H(8)N(2)·2H(2)O}(n), the Mn(II) atom is coordinated in a distorted octa-hedral geometry defined by four O atoms from three different carboxyl-ate ligands and two trans-N atoms from two 4,4'-bipyridine ligands. In the crystal structure, an extensive range of O-H⋯O and O-H⋯N hydrogen bonds link the complex and all no...
متن کاملcatena-Poly[4,4′-bipyridinium [[diaquadisulfatocadmium(II)]-μ-4,4′-bipyridine-κ2 N:N′] dihydrate]
The title compound, {(C(10)H(10)N(2))[Cd(SO(4))(2)(C(10)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), consists of anionic chains of the Cd complex, diprotonated 4,4'-bipyridinium cations and uncoordinated water mol-ecules. In the anionic chain, the Cd atom lies on a center of inversion in an octa-hedral geometry. The midpoint of the coordinated bipyridine also resides on a center of inversion, as does the n...
متن کاملcatena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate]
The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydro-thermal reaction of manganese chloride with mixed 3-hydroxy-lcinnamic acid (H(2)L) and 4,4'-bipyridine (4,4'-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with the Mn(II) atoms lying on a centres of inversion and bridged into a linear chain along the a axis...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2013
ISSN: 1600-5368
DOI: 10.1107/s1600536813000585